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Kinetics and Mechanisms of the Redox Reactions of µ-Adipato-Di (N,N/ Bis(Salicylidene) Ethylenediaminatoiron (Iii) [(Fe-Salen)2adi] with some Thiols

Kinetics and Mechanisms of the Redox Reactions of µ-Adipato-Di (N,N/ Bis(Salicylidene) Ethylenediaminatoiron (Iii) [(Fe-Salen)2adi] with some Thiols. ABSTRACT Electron transfer reactions of Fe2adi was studied with reductants (L-cysteine (LSH),thiourea(USH), thioglycolic acid(GSH), 2-mecarptobenzothiazole (BTSH) and benzyl mercaptan (BSH)). The stoichiometries of the reactions were 1:1 (oxidant/reductant) for LSH, GSH and BTSH while 1:2 (oxidant/reductant) was obtained […]

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